Hydrodeoxygenation processes: Advances on catalytic transformations of biomass-derived platform chemicals into hydrocarbon fuels

被引：296

作者：

De, Sudipta ^{[1
]}

Saha, Basudeb ^{[1
,2
,3
]}

Luque, Rafael ^{[4
]}

机构：

[1] Univ Delhi, Dept Chem, Catalysis Lab, Delhi 110007, India

[2] Purdue Univ, Dept Chem, W Lafayette, IN 47906 USA

[3] Purdue Univ, Ctr Direct Catalyt Convers Biomass Bioenergy C3Bi, W Lafayette, IN 47906 USA

[4] Univ Cordoba, Dept Quim Organ, Cordoba 14014, Spain

来源：

BIORESOURCE TECHNOLOGY | 2015年 / 178卷

关键词：

Biorefinery; Hydrogenation; Hydrodeoxygenation; C-C coupling; Liquid hydrocarbon; HIGH-QUALITY DIESEL; GAMMA-VALEROLACTONE; LEVULINIC ACID; SELECTIVE HYDROGENATION; PHASE HYDROGENATION; REACTION NETWORK; LIQUID ALKANES; BIO-OILS; CONVERSION; LIGNIN;

D O I：

10.1016/j.biortech.2014.09.065

中图分类号：

S2 [农业工程];

学科分类号：

082806 [农业信息与电气工程];

摘要：

Lignocellulosic biomass provides an attractive source of renewable carbon that can be sustainably converted into chemicals and fuels. Hydrodeoxygenation (HDO) processes have recently received considerable attention to upgrade biomass-derived feedstocks into liquid transportation fuels. The selection and design of HDO catalysts plays an important role to determine the success of the process. This review has been aimed to emphasize recent developments on HDO catalysts in effective transformations of biomass-derived platform molecules into hydrocarbon fuels with reduced oxygen content and improved H/C ratios. Liquid hydrocarbon fuels can be obtained by combining oxygen removal processes (e.g. dehydration, hydrogenation, hydrogenolysis, decarbonylation etc.) as well as by increasing the molecular weight via C-C coupling reactions (e.g. aldol condensation, ketonization, oligomerization, hydroxyalkylation etc.). Fundamentals and mechanistic aspects of the use of HDO catalysts in deoxygenation reactions will also be discussed. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：108 / 118

页数：11

共 75 条

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