Preparation of 1,2,3,4,6-penta-O-galloyl-[U-14C]-D-glucopyranose

被引：12

作者：

Chen, YM ^{[1
]}

Hagerman, AE ^{[1
]}

Minto, RE ^{[1
]}

机构：

[1] Miami Univ, Dept Chem & Biochem, Oxford, OH 45056 USA

来源：

JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS | 2003年 / 46卷 / 01期

关键词：

hydrolyzable tannin; polyphenol; antioxidant; pentagalloylglucose;

D O I：

10.1002/jlcr.648

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

The synthesis of 1,2,3,4,6-penta-O-galloyl-[U-C-14]-D-glucopyranose is described. [U-C-14]glucopyranose was reacted with tri-O-benzylgallic acid forming 1;2,3,4,6-penta(tri-O-benzylgalloyl)-[U-C-14]-D-glucopyranose as chromatograpically separable anomers. Removal of the benzyl group by catalytic hydrogenation afforded 1,2,3,4,6-penta-O-galloyl-[U-C-14]-D-glucopyranose in 54% overall yield. GRAPHICS. Copyright (C) 2002 John Wiley Sons, Ltd.

引用

页码：99 / 105

页数：7

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