Standard reference water samples for rare earth element determinations

被引:62
作者
Verplanck, PL [1 ]
Antweiler, RC [1 ]
Nordstrom, DK [1 ]
Taylor, HE [1 ]
机构
[1] US Geol Survey, Div Water Resources, Boulder, CO 80303 USA
关键词
D O I
10.1016/S0883-2927(00)00030-5
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
Standard reference water samples (SRWS) were collected from two mine sites, one near Ophir, CO, USA and the other near Redding, CA, USA. The samples were filtered, preserved, and analyzed for rare earth element (REE) concentrations (La, Ce, Pr, Nd, Sm, Eu, Cd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) by inductively coupled plasma-mass spectrometry (ICP-MS). These two samples were acid mine waters with elevated concentrations of REEs (0.45-161 mug/l) Seventeen international laboratories participated in a 'round-robin' chemical analysis program, which made it possible to evaluate the data by robust statistical procedures that are insensitive to outliers. The resulting most probable values are reported. Ten to 15 of the participants also reported values for Ba, Y, and Sc. Field parameters, major ion, and other trace element concentrations, not subject to statistical evaluation, are provided. Published by Elsevier Science Ltd.
引用
收藏
页码:231 / 244
页数:14
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