One-dimensional capacitance behavior of electrolytes in a nanopore

被引:8
作者
Tang, YW
Chan, KY
Szalai, I
机构
[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
[2] Univ Veszprem, Dept Phys, H-8201 Veszprem, Hungary
关键词
D O I
10.1021/nl025868x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
One-dimensional capacitor behavior is reported for electrolytes confined in a nanopore. The electrical behavior of a 0.1 M electrolyte confined in a nanopore is studied by equilibrium and nonequilibrium molecular dynamics simulations. For an electrolyte in a nanopore with a radius of 4.5 Angstrom, capacitance character is exhibited at low frequencies. A unique feature of the maximum conductivity at a resonance frequency corresponds to RLC equivalent circuit behavior.
引用
收藏
页码:217 / 221
页数:5
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