Reaction of cyclopentadienyllutetium anthracenide with azobenzene.: Synthesis and molecular and crystal structure of the binuclear complex [C5H5(THF)Lu(μ-η2:η2-PhN-NPh)]2(THF)2 and its dynamic behavior in solution

被引：9

作者：

Roitershtein, DM

Lyssenko, KA

Belyakov, PA

Antipin, MY

Petrov, ES

机构：

[1] LY Karpov Phys Chem Res Inst, State Sci Ctr Russian Federat, Moscow 103064, Russia

[2] AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia

[3] Russian Acad Sci, Higher Chem Coll, Moscow 125820, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1997年 / 46卷 / 09期

关键词：

organolanthanide compounds; lutetium; azobenzene; complex; molecular and crystal structure;

D O I：

10.1007/BF02502946

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the cyclopentadienyllutetium anthracenide, C5H5Lu(C14H10)(2-)(THF)(2) (1), with azobenzene yielded the [C5H5(THF)Lu(mu-eta(2):eta(2)-PhN-NPh)](2)(THF)(2) (2) binuclear complex. The structure of the reaction product was established by X-ray structural analysis. The dynamic behavior of complex 2 in a THF-d(g) solution was studied by H-1 NMR spectroscopy in the temperature range of 265-330 K.

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收藏

页码：1590 / 1594

页数：5

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