Complexation of C60 with hexahomooxacalix[3]arenes and supramolecular structures of complexes in the solid state

被引：98

作者：

Tsubaki, K

Tanaka, K

Kinoshita, T

Fuji, K ^{[1
]}

机构：

[1] Kyoto Univ, Inst Chem Res, Uji, Kyoto 6110011, Japan

[2] Fujisawa Pharmaceut Co Ltd, Basic Res Labs, Yodogawa Ku, Osaka 5328514, Japan

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 08期

关键词：

D O I：

10.1039/a800078f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hexahomooxacalix[3]arenes 1-5, which possess a variety of substituents on their upper rim, have captured fullerene C-60 in toluene with association constants of K-a = 9.1-35.6 dm(3) mol(-1); X-ray analysis of the complex of C-60 and 4 indicated that a van der Waals attractive interaction is the dominant driving force which brings the hexagonal faces of the C-60 close to both the aromatic rings and the dibenzyl ether oxygen of 4.

引用

页码：895 / 896

页数：2

共 20 条

[1] A GAS-PHASE CONTAINER FOR C-60 - A GAMMA-CYCLODEXTRIN DIMER
ANDERSSON, T
WESTMAN, G
STENHAGEN, G
SUNDAHL, M
WENNERSTROM, O
[J]. TETRAHEDRON LETTERS, 1995, 36 (04) : 597 - 600
[2] Molecular design of calixarene-based host molecules for inclusion of C-60 in solution
Araki, K
Akao, K
Ikeda, A
Suzuki, T
Shinkai, S
[J]. TETRAHEDRON LETTERS, 1996, 37 (01) : 73 - 76
[3] PURIFICATION OF C-60 AND C-70 BY SELECTIVE COMPLEXATION WITH CALIXARENES
ATWOOD, JL
KOUTSANTONIS, GA
RASTON, CL
[J]. NATURE, 1994, 368 (6468) : 229 - 231
[4] ATWOOD JL, 1996, J CHEM SOC CHEM COMM, P1449
[5] PREPARATION AND CHARACTERIZATION OF C-60(FERROCENE)2
CRANE, JD
HITCHCOCK, PB
KROTO, HW
TAYLOR, R
WALTON, DRM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (24) : 1764 - 1765
[6] CRYSTALLOGRAPHIC CHARACTERIZATION OF THE LATTICE STRUCTURE C60[FE4(CO)4(ETA-5-C5H5)4] AS THE 1/3 BENZENE SOLVATE
CRANE, JD
HITCHCOCK, PB
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (16): : 2537 - 2538
[7] CALIXARENES .10. OXACALIXARENES
DHAWAN, B
GUTSCHE, CD
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (09) : 1536 - 1539
[8] DIEDERICH F, 1992, ANGEW CHEM INT EDIT, V31, P1599
[9] [60]FULLERENE AND TCNQ DONOR-ACCEPTOR CRYSTALS OF OCTAKIS(DIMETHYLAMINO)PORPHYRAZINE
EICHHORN, DM
YANG, SL
JARRELL, W
BAUMANN, TF
BEALL, LS
WHITE, AJP
WILLIAMS, DJ
BARRETT, AGM
HOFFMAN, BM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (16) : 1703 - 1704
[10] New supramolecular complex of C-60 based on calix[5]arene - Its structure in the crystal and in solution
Haino, T
Yanase, M
Fukazawa, Y
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (03): : 259 - 260

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