Metasomatized harzburgite xenoliths from Avacha volcano as fragments of mantle wedge of the Kamchatka arc: Implication for the metasomatic agent

Abundant peridotite xenoliths have been found in pyroclasitics of Avacha (Avachinsky) volcano, the south Kamchatka arc, Russia. They are mostly refractory harzburgite with or without clinopyroxene: the Fo of olivine and Cr/(Cr + Al) atomic ratio of spinel range from 91 to 92 and from 0.5 to 0.7, respectively. They are metasomatized to various extents, and the metasomatic orthopyroxene has been formed at the expense of olivine. The metasomatic orthopyroxene, free of deformation and exsolution, is characterized by low contents of CaO and Cr2O3. The complicated way of replacement possibly indicates low viscosity of the metasomatic agent, namely hydrous fluids released from the relatively cool slab beneath the south Kamchatka arc. This is a good contrast to the north Kamchatka arc, where the slab has been hot enough to provide slab-derived melts. High content of total orthopyroxene, 40 vol% on average, in metasomatized harzburgite from Avacha suggests silica enrichment of the mantle wedge, and is equivalent to some subcratonic harzburgite. Some subcratonic harzburgites therefore could have been formed by transportation of subarc metasomatized peridotites to a deeper part of the upper mantle.