Metal ion-doped SnO2 ordered porous films and their strong gas sensing selectivity

被引:41
作者
Jia, Lichao [1 ]
Cai, Weiping [1 ]
Wang, Hongqiang [1 ]
机构
[1] Chinese Acad Sci, Key Lab Mat Phys, Anhui Key Lab Nanomat & Nanotechnol, Inst Solid State Phys, Hefei 230031, Peoples R China
基金
安徽省自然科学基金;
关键词
ZNO NANOTUBES; SENSORS; ETHANOL; CO;
D O I
10.1063/1.3358389
中图分类号
O59 [应用物理学];
学科分类号
摘要
Based on a sol-gel technique and the colloidal monolayer template, ion-doped SnO2 ordered porous films were fabricated, and the corresponding gas-sensing properties were studied. The sensitivity to the given test gases strongly depends on the doping species and doping amount. Importantly, when the doping amount is 1% M, the Cr+3 and Pd+2 doped porous films demonstrate a greatly enhanced sensitivity and strong selectivity to ethanol and ammonia, respectively. The improved sensing properties are attributed to the doping-induced surface modification of the films. Such ion-doped porous films are expected to bring new opportunities for application of future porous film-based gas sensors. (C) 2010 American Institute of Physics. [doi: 10.1063/1.3358389]
引用
收藏
页数:3
相关论文
共 21 条
[1]   A highly sensitive and fast-responding ethanol sensor based on CdIn2O4 nanocrystals synthesized by a nonaqueous sol-gel route [J].
Cao, Minhua ;
Wang, Yude ;
Chen, Ting ;
Antonietti, Markus ;
Niederberger, Markus .
CHEMISTRY OF MATERIALS, 2008, 20 (18) :5781-5786
[2]   AMMONIA DISSOCIATION ON OXYGEN COVERED PALLADIUM STUDIED WITH A HYDROGEN SENSITIVE PD-MOS DEVICE [J].
FOGELBERG, J ;
LUNDSTROM, I ;
PETERSSON, LG .
PHYSICA SCRIPTA, 1987, 35 (05) :702-705
[3]   Metal and metal oxide nanoparticles in chemiresistors: Does the nanoscale matter? [J].
Franke, ME ;
Koplin, TJ ;
Simon, U .
SMALL, 2006, 2 (01) :36-50
[4]   A selective nanosensing probe for nitric oxide [J].
Gouma, P. I. ;
Kalyanasundaram, K. .
APPLIED PHYSICS LETTERS, 2008, 93 (24)
[5]   Layer-by-layer strategy for the general synthesis of 2D ordered micro/nanostructured porous arrays: structural, morphological and compositional controllability [J].
Jia, Lichao ;
Cai, Weiping ;
Wang, Hongqiang .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (39) :7301-7307
[6]   Hetero-apertured Micro/Nanostructured Ordered Porous Array: Layer-by-Layered Construction and Structure-Induced Sensing Parameter Controllability [J].
Jia, Lichao ;
Cai, Weiping ;
Wang, Hongqiang ;
Sun, Fengqiang ;
Li, Yue .
ACS NANO, 2009, 3 (09) :2697-2705
[7]   Gas detection using low-temperature reduced graphene oxide sheets [J].
Lu, Ganhua ;
Ocola, Leonidas E. ;
Chen, Junhong .
APPLIED PHYSICS LETTERS, 2009, 94 (08)
[8]   SnO2-In2O3 nanocomposites as semiconductor gas sensors for CO and NOx detection [J].
McCue, Justin T. ;
Ying, Jackie Y. .
CHEMISTRY OF MATERIALS, 2007, 19 (05) :1009-1015
[9]   Cr-Sn oxide thin films:: Electrical and spectroscopic characterisation with CO, NO2, NH3 and ethanol [J].
Morandi, S. ;
Comini, E. ;
Faglia, G. ;
Ghiotti, G. .
SENSORS AND ACTUATORS B-CHEMICAL, 2006, 118 (1-2) :142-148
[10]   BINDING-ENERGY SHIFTS IN X-RAY PHOTOELECTRON SPECTRA OF A SERIES OF RELATED GROUP IV-A COMPOUNDS [J].
MORGAN, WE ;
VANWAZER, JR .
JOURNAL OF PHYSICAL CHEMISTRY, 1973, 77 (07) :964-969