Aluminum dodecatungstophosphate (AIPW12O40) as a non-hygroscopic Lewis acid catalyst for the efficient Friedel-Crafts acylation of aromatic compounds under solvent-less conditions

被引：74

作者：

Firouzabadi, H ^{[1
]}

Iranpoor, N ^{[1
]}

Nowrouzi, F ^{[1
]}

机构：

[1] Shiraz Univ, Dept Chem, Shiraz 71454, Iran

来源：

TETRAHEDRON | 2004年 / 60卷 / 48期

关键词：

Freidel-Crafts acylation; poly oxometalate; aluminum dodecatungstophosphate; solvent-free;

D O I：

10.1016/j.tet.2004.09.049

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Stable and non-hygroscopic aluminum dodecatungstophosphate (AlPW12O40), which is prepared easily from cheap and commercially available compounds was found to be an effective catalyst for Friedel-Crafts acylation reactions using carboxylic acids, acetic anhydride and benzoyl chloride in the absence of solvent under mild reaction conditions. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：10843 / 10850

页数：8

共 58 条

[1]

AOSHIMA A, 1985, SHOKUBAI, V27, P386

[2]

Aoshima A, 1990, POLYM ADVAN TECHNOL, V1, P127

[3]

BABA T, 1983, PHYS CHEM, V87, P2406

[4]

BARBERO M, 1990, GAZZ CHIM ITAL, V120, P619