Coalescence in draining foams

被引:101
作者
Carrier, V [1 ]
Colin, A [1 ]
机构
[1] Ctr Rech Paul Pascal, CNRS, F-33600 Pessac, France
关键词
D O I
10.1021/la026995b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cellular material (emulsions, foams) made out of two different phases, one dispersed in another, may coarsen with time through coalescence, which is the rupture of the thin liquid film that separates two adjacent droplets or bubbles. In this Letter, we study destruction through coalescence of a model cellular material: a monodisperse soap foam. We report the existence of a sharp destabilization threshold controlled only by the liquid fraction of the foam at which the rate of coalescence increases dramatically. We point out a coupling between drainage and coalescence. We suggest that the rearrangements of the bubbles during the drainage of the foam induce an increase of the area of the bubbles which decreases temporarily the amount of adsorbed surfactant by unit area and weakens the interfaces.
引用
收藏
页码:4535 / 4538
页数:4
相关论文
共 30 条
[1]   ELECTRICAL-CONDUCTIVITY AND THE DISTRIBUTION OF LIQUID IN POLYHEDRAL FOAM [J].
AGNIHOTRI, AK ;
LEMLICH, R .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1981, 84 (01) :42-46
[2]   Disjoining pressures and film stability of alkyltrimethylammonium bromide foam films [J].
Bergeron, V .
LANGMUIR, 1997, 13 (13) :3474-3482
[3]   STABILITY-CRITERIA FOR EMULSIONS [J].
BIBETTE, J ;
MORSE, DC ;
WITTEN, TA ;
WEITZ, DA .
PHYSICAL REVIEW LETTERS, 1992, 69 (16) :2439-2442
[4]   STRUCTURE AND DYNAMICS OF BREAKING FOAMS [J].
BURNETT, GD ;
CHAE, JJ ;
TAM, WY ;
DEALMEIDA, RMC ;
TABOR, M .
PHYSICAL REVIEW E, 1995, 51 (06) :5788-5796
[5]   Dynamics of foams with and without wall rupture [J].
Chae, JJ ;
Tabor, M .
PHYSICAL REVIEW E, 1997, 55 (01) :598-610
[6]   LIQUID DISTRIBUTION AND ELECTRICAL-CONDUCTIVITY IN FOAM [J].
DATYE, AK ;
LEMLICH, R .
INTERNATIONAL JOURNAL OF MULTIPHASE FLOW, 1983, 9 (06) :627-636
[7]   Young soap films [J].
de Gennes, PG .
LANGMUIR, 2001, 17 (08) :2416-2419
[8]  
EXEROWA D, 1987, COLLOID SURFACE, V22, P171
[9]  
FINDLAY S, 1997, THESIS DUBLIN
[10]   Interbubble gas diffusion and the stability of foams [J].
Gandolfo, FG ;
Rosano, HL .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1997, 194 (01) :31-36