Hypervalent iodine-mediated vicinal syn diazidation:: Application to the total synthesis of (±)-dibromophakellstatin

被引：89

作者：

Chung, R ^{[1
]}

Yu, ES ^{[1
]}

Incarvito, CD ^{[1
]}

Austin, DJ ^{[1
]}

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 22期

关键词：

D O I：

10.1021/ol0490532

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The total synthesis of (+/-)-dibromophakellstatin is described. The molecule is constructed from a key syn-diazide, formed by a hypervalent iodine-mediated diazidation of a dihydrodipyrrolopyrazinone ring structure.

引用

页码：3881 / 3884

页数：4

共 36 条

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