Spectroscopic behaviour of metal-drug complexes. Infrared spectra of Cu(II) complexes with 5-amino-1,3,4-thiadiazole-2-thiol(Hatm)

被引：59

作者：

Chufan, EE

Pedregosa, JC

Borras, J

机构：

[1] Univ Nacl San Luis, Fac Quim Bioquim & Farm, PID, CONICET, RA-5700 San Luis, Argentina

[2] Univ Valencia, Fac Farm, E-46010 Valencia, Spain

来源：

VIBRATIONAL SPECTROSCOPY | 1997年 / 15卷 / 02期

关键词：

infrared spectrometry; Raman spectrometry; copper (II); metal-drug complexes vibrations; 5-amino-1,3,4-thiadiazole-2-thiol;

D O I：

10.1016/S0924-2031(97)00033-7

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The infrared spectra of the drug Hatm and its copper (II) complexes with stoichiometry [Cu(atm)(2)(H2O)] and [Cu(Hatm)(HIm)(2)(SO4)] are reported and discussed. The Raman spectrum of Hatm is also reported. An assignment of Hatm, HIm, H2O and SO4 modes in the complexes is proposed in comparison with the modes of the free ligands. Important information about the metal-ligand vibrations has been obtained. (C) 1997 Elsevier Science B.V.

引用

页码：191 / 199

页数：9

共 42 条

[1] ANTICONVULSANT PROPERTIES OF COPPER ACETAZOLAMIDE COMPLEXES [J].