Synthesis and characterization of the monomer Ga{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6):: a low valent gallium(I) carbene analogue

被引：304

作者：

Hardman, NJ ^{[1
]}

Eichler, BE ^{[1
]}

Power, PP ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 20期

关键词：

D O I：

10.1039/b005686n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction between solvent free Li{(NDippCMe)(2)CH} (Dipp = C6H3Pr2i-2,6), 'GaI' and potassium in toluene afforded Ga{(NDippCMe)(2)CH} 1 which features a V-shaped, two-coordinate, six-electron gallium(I) center electronically analogous to a singlet carbene carbon.

引用

页码：1991 / 1992

页数：2

共 20 条

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