Marked dependence on temperature of enantioselectivity in the Aspergillus oryzae protease-catalyzed hydrolysis of amino acid esters

被引:7
作者
Miyazawa, T [1 ]
Imagawa, K [1 ]
Yanagihara, R [1 ]
Yamada, T [1 ]
机构
[1] Konan Univ, Fac Sci, Dept Chem, Higashinada Ku, Kobe, Hyogo 658, Japan
关键词
D O I
10.1023/A:1018478703936
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
In the Aspergillus oryzae protease-catalyzed enantioselective hydrolysis of amino acid esters, linear relationships were observed between-RTInE and T, where E=enantiomeric ratio and T=absolute temperature. According to this temperature dependence, the E value of 11 at 45 degrees C was enhanced to 140 at 5 degrees C in a typical example.
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收藏
页码:931 / 933
页数:3
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