Kumada-Corriu Cross-Couplings with 2-Pyridyl Grignard Reagents

被引：91

作者：

Ackermann, Lutz ^{[1
]}

Potukuchi, Harish K. ^{[1
]}

Kapdi, Anant R. ^{[1
]}

Schulzke, Carola ^{[2
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany

[2] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 11期

关键词：

cross-coupling; heteroarenes; organomagnesium reagents; palladium; pyridines; secondary phosphine oxides; CARBON BOND-FORMATION; PHOSPHINE OXIDES; C-C; DIRECT ARYLATION; ALKYL-HALIDES; ARYL; ACTIVATION; PRELIGANDS; CATALYSIS; LIGAND;

D O I：

10.1002/chem.201000032

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chemical Equation Presentation SPOs meet the challenge: A palladium complex derived from air- and moisture-stable secondary phosphine oxide (SPO) (1-Ad)2P(O)H enables general cross-coupling reactions of challenging electron-deficient 2-pyridyl Grignard reagents with ample scope (see scheme) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3300 / 3303

页数：4

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