Chemistry in confined geometries:: Reactions at an organic surface

被引：16

作者：

Rajalingam, Ketheeswari ^{[1
]}

Bashir, Asif ^{[1
]}

Badin, Mihaela ^{[1
]}

Schroeder, Felicitas ^{[1
]}

Hardman, Ned ^{[1
]}

Strunskus, Thomas ^{[1
]}

Fischer, Roland A. ^{[1
]}

Woell, Christof ^{[1
]}

机构：

[1] Ruhr Univ Bochum, D-44780 Bochum, Germany

来源：

CHEMPHYSCHEM | 2007年 / 8卷 / 05期

关键词：

monolayers; nucleation; organothiols; self-assembly; surface chemistry;

D O I：

10.1002/cphc.200700044

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two-dimensional reactions: Modification of organothiol self-assembled monolayers (SAMs) adsorbed on solid surfaces opens new possibilities for applications of such systems. However, reactions at organic monolayers display vastly different kinetics than in solution and are shown to initiate at defects in the monolayer structure and proceed along a one-dimensional reaction front (see picture) (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：657 / 660

页数：4

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