A novel 3-D chiral coordination polymer:: hydrothermal synthesis and structural characterization of [Co3(μ3-OH)([μ5-btc)(μ6-Hbtc)(H2O)3 • 6H2O]n

被引：35

作者：

Lü, ZL

Chen, W

Xu, JQ ^{[1
]}

Zhang, LJ

Pan, CL

Wang, TG

机构：

[1] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China

[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 03期

基金：

中国国家自然科学基金;

关键词：

hydrothermal; open-framework; benzene-1,2,4-tricarboxylate; coordination polymer;

D O I：

10.1016/S1387-7003(02)00751-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A chiral 3-D open-framework coordination polymer [Co-3(mu(3)-OH)(mu(5)-btc)(mu(6)-Hbtc)(H2O)(3) . 6H(2)O]n was successfully obtained from the mixture of Co(CH3COO)(2) . 4H(2)O, H(3)btc (where H(3)btc = benzene- 1,2,4-tricarboxylic acid), NaOH and H2O under hydrothermal condition, which contains a novel and unprecedented coordination mode of btc (see Scheme 1). (C) 2002 Elsevier Science B.V. All rights reserved.

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页码：244 / 248

页数：5

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