First Heck reaction with arenediazonium cations with recovery of Pd-triolefinic macrocyclic catalyst

被引：122

作者：

Masllorens, J ^{[1
]}

Moreno-Mañas, M

Pla-Quintana, A

Roglans, A

机构：

[1] Univ Girona, Dept Chem, Girona 17071, Spain

[2] Univ Autonoma Barcelona, Dept Chem, E-08193 Barcelona, Spain

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 09期

关键词：

D O I：

10.1021/ol034340b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

dThe air- and moisture-stable phosphine-free palladium(0) complex 1 is a highly active and recoverable catalyst for Heck olefination of aryl diazonium tetrafluoroborates. The reactions were performed under aerobic conditions at room temperature to give the coupling products in excellent yields.

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收藏

页码：1559 / 1561

页数：3

相关论文

共 40 条

[1] OBSERVATION OF CATALYTIC INTERMEDIATES IN THE SUZUKI REACTION BY ELECTROSPRAY MASS-SPECTROMETRY [J].

ALIPRANTIS, AO ;

CANARY, JW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (15) :6985-6986

[2] Palladium-imidazolium carbene catalyzed Mizoroki-Heck coupling with aryl diazonium ions [J].

Andrus, MB ;

Song, C ;

Zhang, JQ .

ORGANIC LETTERS, 2002, 4 (12) :2079-2082

[3] Electrospray ionization mass spectrometry detection of intermediates in the palladium-catalyzed oxidative self-coupling of areneboronic acids [J].

Aramendía, MA ;

Lafont, F ;

Moreno-Mañas, M ;

Pleixats, R ;

Roglans, A .

JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (10) :3592-3594

[4] The heck reaction as a sharpening stone of palladium catalysis [J].

Beletskaya, IP ;

Cheprakov, AV .

CHEMICAL REVIEWS, 2000, 100 (08) :3009-3066

[5]

BELLER M, 1995, SYNLETT, P441

[6] TANDEM DIAZOTIZATION HECK REACTIONS - A GENERAL-SYNTHESIS OF SUBSTITUTED STYRENES FROM ANILINES [J].

BELLER, M ;

FISCHER, H ;

KUHLEIN, K .

TETRAHEDRON LETTERS, 1994, 35 (47) :8773-8776

[7]

Beller M., 2002, HDB ORGANOPALLADIUM, P1209

[8] Characterization of reactive intermediates in palladium-catalyzed arylation of methyl acrylate (Heck reaction) [J].

Brown, JM ;

Hii, KK .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (06) :657-659

[9] Application of a new combination of palladium and CaCO3 for an aerobic heck reaction using arenediazonium-salts [J].

Brunner, H ;

de Courcy, NLC ;

Genêt, JP .

TETRAHEDRON LETTERS, 1999, 40 (26) :4815-4818

[10] RECENT DEVELOPMENTS AND NEW PERSPECTIVES IN THE HECK REACTION [J].

CABRI, W ;

CANDIANI, I .

ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (01) :2-7

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