Synthesis and electroluminescent properties of copolymers derived from fluorene and thiophene derivatives

被引：8

作者：

Hou, Q ^{[1
]}

Niu, H ^{[1
]}

Huang, WB ^{[1
]}

Yang, W ^{[1
]}

Yang, RQ ^{[1
]}

Yuan, M ^{[1
]}

Cao, Y ^{[1
]}

机构：

[1] S China Univ Technol, Inst Polymer Optoelect Mat & Devices, Guangzhou 510640, Peoples R China

来源：

SYNTHETIC METALS | 2003年 / 135卷 / 1-3期

关键词：

polyfluorene; copolymers; Suzuki coupl ing;

D O I：

10.1016/S0379-6779(02)00632-X

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A series of novel soluble conjugated copolymers derived from 9,9-dioctylfluorene (DOF) with thiophene (TOP), ethylenedioxythiophene (EDT) were synthesized via palladium-catalyzed Suzuki coupling reaction. The copolymers of DOFco-EDT and DOF-co-TOP give rise to various emission colors from bluish-green to yellow. Highest electroluminescent (EL) quantum efficiencies of the devices based on the copolymers were 1.8% for DOF-co-EDT, 0.45% for DOF-co-TOP, respectively. Enhanced quantum efficiency for devices from these copolymers makes them a promising candidate for PLED displays.

引用

页码：185 / 186

页数：2

共 8 条

[1]

Bernius MT, 2000, ADV MATER, V12, P1737, DOI 10.1002/1521-4095(200012)12:23<1737::AID-ADMA1737>3.0.CO

[2]

2-N

[3] Light-emitting diodes from fluorene-based π-conjugated polylmers [J].

Donat-Bouillud, A ;

Lévesque, I ;

Tao, Y ;

D'Iorio, M ;

Beaupré, S ;

Blondin, P ;

Ranger, M ;

Bouchard, J ;

Leclerc, M .

CHEMISTRY OF MATERIALS, 2000, 12 (07) :1931-1936

[4] Absorption properties of alkoxy-substituted thienylene-vinylene oligomers as a function of the doping level [J].

Havinga, EE ;

Mutsaers, CMJ ;

Jenneskens, LW .

CHEMISTRY OF MATERIALS, 1996, 8 (03) :769-776

[5]

KLAMER G, 1999, ADV MATER, V11, P115

[6] Polyfluorenes: Twenty years of progress [J].

Leclerc, M .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2001, 39 (17) :2867-2873

[7] New well-defined poly(2,7-fluorene) derivatives: Photoluminescence and base doping [J].

Ranger, M ;

Rondeau, D ;

Leclerc, M .

MACROMOLECULES, 1997, 30 (25) :7686-7691

[8] Electroactive and luminescent polymers: new fluorene-heterocycle-based hybrids [J].

Tsuie, B ;

Reddinger, JL ;

Sotzing, GA ;

Soloducho, J ;

Katritzky, AR ;

Reynolds, JR .

JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (09) :2189-2200

← 1 →