Palladium- and nickel-catalyzed coupling reactions of α-bromoalkenylphosphonates with arylboronic acids and lithium alkenylborates

被引：42

作者：

Kobayashi, Y ^{[1
]}

William, AD ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Biomol Engn, Midori Ku, Yokohama, Kanagawa 2268501, Japan

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2004年 / 346卷 / 13-15期

关键词：

boranes; borates; cross-coupling; nickel; palladium; phosphonates;

D O I：

10.1002/adsc.200404191

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The coupling reaction of the alpha-bromoalkenylphosphonates with organoboranes was investigated. The palladium-catalyzed arylation took place successfully with arylboronic acids, while alkenylation proceeded with lithium alkenylborates and a nickel catalyst. In addition, an intramolecular Diels-Alder reaction of the diene prepared by the alkenylation afforded the corresponding adduct.

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页码：1749 / 1757

页数：9

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