Diaquabis(2-pyridinecarboxylato-N,O)-manganese(II)

被引:24
作者
Okabe, N [1 ]
Koizumi, M [1 ]
机构
[1] Kinki Univ, Fac Pharmaceut Sci, Osaka 577, Japan
关键词
D O I
10.1107/S0108270197016326
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the title compound, [Mn(C6H4NO2)(2)(H2O)(2)], the Mn-II atom has a distorted octahedral coordination geometry defined by two N atoms of the pyridine rings, two O atoms of the carboxylate groups and two O atoms of the water molecules; all of the corresponding pairs of the ligand atoms lie in cis positions. The carboxylate group is nearly coplanar with the pyridine ring. The crystal structure is stabilized by intermolecular O-H ... O hydrogen bonds involving all water H atoms and the carboxylato groups.
引用
收藏
页码:288 / 290
页数:3
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