The hydride route to the preparation of dinitrogen complexes

被引：103

作者：

Ballmann, Joachim ^{[1
]}

Munha, Rui F. ^{[1
]}

Fryzuk, Michael D. ^{[1
]}

机构：

[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 07期

基金：

加拿大自然科学与工程研究理事会;

关键词：

MOLECULAR-HYDROGEN COMPLEXES; ON-BOUND DINITROGEN; NONCLASSICAL DIHYDROGEN COMPLEXES; ZEROVALENT OLEFINIC DERIVATIVES; RAY CRYSTAL-STRUCTURES; BRIDGING N-2 UNIT; N BOND-CLEAVAGE; SIDE-ON; X-RAY; COORDINATED DINITROGEN;

D O I：

10.1039/b922853e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

That the inert dinitrogen molecule can act as a ligand to a transition metal complex is one of the key discoveries in inorganic chemistry of the past century. This feature article summarises a body of work up to 2010 that describes a particularly attractive route to dinitrogen complexes that involves the direct reaction of N-2 with metal hydride derivatives. This process is shown to be general across the transition series and, depending on the metal, different levels of activation of the coordinated dinitrogen unit are observed.

引用

页码：1013 / 1025

页数：13

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