Tandem cross-metathesis/hydrogenation/cyclization reactions by using compatible catalysts

被引：88

作者：

Cossy, J ^{[1
]}

Bargiggia, F ^{[1
]}

BouzBouz, S ^{[1
]}

机构：

[1] Ecole Super Phys & Chim Ind Ville Paris, CNRS, Chim Organ Lab, F-75231 Paris 05, France

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 04期

关键词：

D O I：

10.1021/ol027347m

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A one-pot tandem cross-metathesis/hydrogenation/cyclization procedure was achieved at room temperature, under 1 atm of hydrogen, in the presence of a ruthenium catalyst and PtO2 showing the compatibility of the two catalysts. This tandem reaction allows the synthesis of substituted lactones and lactols from acrylic acid and acrolein, respectively, in the presence of unsaturated alcohols.

引用

页码：459 / 462

页数：4

共 20 条

[1] [Anonymous], 1998, TRANSITION METALS OR
[2] Synthesis of branched polyolefins using a combination of homogeneous metallocene mimics
Barnhart, RW
Bazan, GC
Mourey, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (05) : 1082 - 1083
[3] SYNTHESIS OF BOTH ENANTIOMERS OF GAMMA-SUBSTITUTED ALPHA, BETA-UNSATURATED GAMMA-LACTONES
BLOCH, R
GILBERT, L
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (20) : 4603 - 4605
[4] Tandem ring-closing metathesis and hydrogenation towards cyclic dinucleotides
Borsting, P
Nielsen, P
[J]. CHEMICAL COMMUNICATIONS, 2002, (18) : 2140 - 2141
[5] SYNTHESIS OF THE (4S,5R)-5-HYDROXY-DECAN-4-OLIDE (L-FACTOR) AND OF THE (R)-DECAN-4-OLIDE FROM A CHIRAL SULFOXIDE
BRAVO, P
RESNATI, G
VIANI, F
ARNONE, A
[J]. TETRAHEDRON, 1987, 43 (20) : 4635 - 4647
[6] Tandem reaction by using compatible catalysts: cross-metathesis reaction and hydrogenation
Cossy, J
Bargiggia, FC
BouzBouz, S
[J]. TETRAHEDRON LETTERS, 2002, 43 (38) : 6715 - 6717
[7] Multiple tandem catalysis: Facile cycling between hydrogenation and metathesis chemistry
Drouin, SD
Zamanian, F
Fogg, DE
[J]. ORGANOMETALLICS, 2001, 20 (26) : 5495 - 5497
[8] Regio- and diastereoselective tandem rhodium-catalyzed allylic alkylation Pauson-Khand annulation reactions
Evans, PA
Robinson, JE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (19) : 4609 - 4610
[9] Efficient and recyclable monomeric and dendritic Ru-based metathesis catalysts
Garber, SB
Kingsbury, JS
Gray, BL
Hoveyda, AH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (34) : 8168 - 8179
[10] SEQUENTIAL ONE-POT ALDOL REACTIONS CATALYZED BY 2-DEOXYRIBOSE-5-PHOSPHATE ALDOLASE AND FRUCTOSE-1,6-DIPHOSPHATE ALDOLASE
GIJSEN, HJM
WONG, CH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (10) : 2947 - 2948

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