Synthesis of the mixed lithium-magnesium, mixed amide (R,R/S,S)-[{LiMg(TMP)[CH2Si(Me)2N(SiMe3)]}2]:: a conformationally-locked structure of five fused rings inducing two stereogenic nitrogen centres

被引：17

作者：

Barr, L ^{[1
]}

Kennedy, AR ^{[1
]}

MacLellan, JG ^{[1
]}

Moir, JH ^{[1
]}

Mulvey, RE ^{[1
]}

Rodger, PJA ^{[1
]}

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 18期

关键词：

D O I：

10.1039/b004317f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of the magnesium amide Mg(TMP)(2) with the lithium amide LiHMDS is accompanied by an unexpected, sterically-promoted hydrogen transfer/amine elimination process, to yield the novel title compound which is the first such heterometallic composition to contain a heteroleptic amide ligand set.

引用

页码：1757 / 1758

页数：2

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