Magnetically Separable Nanocatalysts: Bridges between Homogeneous and Heterogeneous Catalysis

被引：1326

作者：

Shylesh, Sankaranarayanapillai ^{[1
]}

Schuenemann, Volker ^{[2
]}

Thiel, Werner R. ^{[1
]}

机构：

[1] Tech Univ Kaiserslautern, Fachbereich Chem, D-67663 Kaiserslautern, Germany

[2] Tech Univ Kaiserslautern, Fachbereich Phys, D-67663 Kaiserslautern, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 20期

关键词：

catalysis; heterogenization; magnetic properties; magnetic separation; nanoparticles; IRON-OXIDE NANOPARTICLES; HIGH-SURFACE-AREA; TRANSFER RADICAL POLYMERIZATION; COLLOIDAL COBALT NANOPARTICLES; TRANSITION-METAL COLLOIDS; SIZE-SELECTIVE SYNTHESIS; BAYLIS-HILLMAN REACTION; ONE-POT SYNTHESIS; PLATINUM NANOPARTICLES; GOLD NANOPARTICLES;

D O I：

10.1002/anie.200905684

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recovery and reuse of expensive catalysts after catalytic reactions are important factors for sustainable process management. The aim of this Review is to highlight the progress in the formation and catalytic applications of magnetic nanoparticles and magnetic nanocomposites. Directed functionalization of the surfaces of nanosized magnetic materials is an elegant way to bridge the gap between heterogeneous and homogeneous catalysis. The introduction of magnetic nanoparticles in a variety of solid matrices allows the combination of well-known procedures for catalyst heterogenization with techniques for magnetic separation. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA,.

引用

页码：3428 / 3459

页数：32

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