Dissipative Self-Assembly of a Molecular Gelator by Using a Chemical Fuel

被引：359

作者：

Boekhoven, Job ^{[1
]}

Brizard, Aurelie M. ^{[1
]}

Kowlgi, Krishna N. K. ^{[1
]}

Koper, Ger J. M. ^{[1
]}

Eelkema, Rienk ^{[1
]}

van Esch, Jan H. ^{[1
]}

机构：

[1] Delft Univ Technol, Dept Chem Engn, NL-2628 BL Delft, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 28期

关键词：

aggregation; gels; hydrolysis; non-equilibrium processes; self-assembly; MICROSCALE OBJECTS; DRIVEN; NANOSTRUCTURES; CHEMISTRY; MOTOR; GEL; SURFACTANTS; DERIVATIVES; GENERATION; INTERFACE;

D O I：

10.1002/anie.201001511

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Fueling the future: A fibrillar network (red fibers, see figure) is formed from an activated building block (red), which is obtained from a synthetic gelator (blue) in a dissipative self-assembly process that is fueled by an alkylating agent. When the available energy is depleted, the system reverts to its thermodynamic equilibrium, that is, an isotropic solution. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4825 / 4828

页数：4

共 64 条

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[Anonymous], 2009, ANGEW CHEM

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