The nitrogenase catalyzed N2 dependent HD formation:: a model reaction and its significance for the FeMoco function

被引：53

作者：

Sellmann, D ^{[1
]}

Fürsattel, A ^{[1
]}

Sutter, J ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Inst Anorgan Chem, D-91058 Erlangen, Germany

来源：

COORDINATION CHEMISTRY REVIEWS | 2000年 / 200卷

关键词：

nitrogen fixation; hydrogen; iron sulfur complexes; structure-function;

D O I：

10.1016/S0010-8545(99)00240-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first completely characterized model for the nitrogenase catalyzed 'N-2 dependent HD formation' from D-2 and protons is described. This key reaction of nitrogenases is most plausibly rationalized by the 'open-side' FeMoco model, which enables us to explain the severe constraints imposed on the N-2 dependent HD formation as well as the noncompetitive inhibition of N-2 fixation by CO. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：545 / 561

页数：17

共 32 条

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