Use of bis(oxazoline)-metal complexes as chiral catalysts for asymmetric-Diels-Alder reactions using 2-acetyl-1,4-naphthoquinone as a dienophile

被引：28

作者：

Brimble, MA ^{[1
]}

McEwan, JF ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 24期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1016/S0957-4166(97)00562-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Asymmetric Diels-Alder reactions of 1,4-naphthoquinone and 2-acetyl-1,4-naphthoquinone with cyclopentadiene catalyzed by bis(oxazoline)-metal complexes afforded the corresponding Diels-Alder adducts. Moderate levels of enantiomeric excess were obtained and a number of different reaction conditions evaluated. (C) 1997 Elsevier Science Ltd. All rights reserved.

引用

页码：4069 / 4078

页数：10

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