Controlled/"living" radical polymerization of glycidyl methacrylate at ambient temperature

被引：80

作者：

Krishnan, R ^{[1
]}

Srinivasan, KSV ^{[1
]}

机构：

[1] Cent Leather Res Inst, Div Polymer, Madras 600020, Tamil Nadu, India

来源：

MACROMOLECULES | 2003年 / 36卷 / 06期

关键词：

D O I：

10.1021/ma025637c

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Controlled/'living' radical polymerization of glycidyl methacrylate at ambient temperature was demonstrated. Poly(glycidylmethacrylate) was synthesized using copper(I) bromide complexed by N-(n-propyl)-2-pyridylmethanimine ligand as catalyst and 2-bromopropionitrile as an initiator in bulk and various solvents. Linear increase of molecular weights with conversion and low polydispersity indices were obtained in the atom transfer radical polymerization of glycidyl methacrylate.

引用

页码：1769 / 1771

页数：3

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