Mechanism and kinetics model of degradation of synthetic dyes by UV-vis/H2O2/ferrioxalate complexes

被引：65

作者：

Dong, Xiaoli

Ding, Wei

Zhang, Xiufang

Liang, Xinmiao ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Grp 1083, Dalian 116023, Peoples R China

[2] Dalian Inst Light Ind, Dalian 116034, Peoples R China

来源：

DYES AND PIGMENTS | 2007年 / 74卷 / 02期

关键词：

photocatalysis; dye; degradation; kinetics;

D O I：

10.1016/j.dyepig.2006.03.008

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The kinetics of photocatalytic degradation of Reactive Brilliant blue KN-R, Acid Scarlet GR and Reactive Brilliant red X-3B by UV-vis/ H2O2/Ferrioxalate complexes were studied. Effects of initial concentration of KN-R solution, Fe2+, H2O2, and pH were investigated. Under these optimum experimental conditions, the removal rates of COD and TOC of three dyes were more than 80% and 65%. A pseudo-first-order kinetic model was adopted to represent the reaction. (c) 2006 Elsevier Ltd. All rights reserved.

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收藏

页码：470 / 476

页数：7

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