On the competitive intramolecular H-bonding in alcohols with two accepting sites

被引：20

作者：

Langoor, MH

vanderMaas, JH

机构：

[1] Analytical Molecular Spectrometry, Utrecht University, 3584 CA Utrecht

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1997年 / 403卷 / 03期

关键词：

hydrogen bonding; competitive interaction; alcohol; infrared spectroscopy;

D O I：

10.1016/S0022-2860(96)09412-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Alcohols with two accepting sites were studied in dilute CCl4 solution by infrared spectroscopy. The results showed that conformer populations based on peak intensities can lead to erroneous conclusions regarding preferred interactions, when the effects of entropy and structural degeneracy become important. For quantitative calculations, peak areas are to be preferred over peak heights. (C) 1997 Elsevier Science B.V.

引用

页码：213 / 229

页数：17

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