A self-assembled light-harvesting array of seven porphyrins in a wheel and spoke architecture

被引：88

作者：

Ambroise, A ^{[1
]}

Li, JZ ^{[1
]}

Yu, LH ^{[1
]}

Lindsey, JS ^{[1
]}

机构：

[1] N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 17期

关键词：

D O I：

10.1021/ol006036d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A shape persistent cyclic array of six zinc porphyrins provides an effective host for a dipyridyl-substituted free base porphyrin, yielding a self-assembled structure for studies of light harvesting. Energy transfer occurs essentially quantitatively from uncoordinated to pyridyl-coordinated zinc porphyrins in the cyclic array. Energy transfer from the coordinated zinc porphyrin to the guest free base porphyrin is less efficient (Phi(trans) similar to 40%) and is attributed to a Forster through space process.

引用

页码：2563 / 2566

页数：4

共 22 条

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