Correlation of the frontier orbital properties of alkanolamines with the experimental CO2 loading

被引：14

作者：

Suda, T

Zhang, Y

Iwaki, T

Nomura, M

机构：

[1] Kansai Elect Power Co Inc, Gen Off Plantsiting & Environm, Kita Ku, Osaka 53070, Japan

[2] Mitsubishi Heavy Ind Ltd, Hiroshima Res & Dev Ctr, Nishi Ku, Hiroshima 733, Japan

[3] Osaka Univ, Fac Engn, Dept Appl Chem, Osaka 565, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 02期

关键词：

D O I：

10.1246/cl.1998.189

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The HOMO energy and the superdelocalizability for the most stable conformation of 18 kinds of alkanolamines plotted against experimentally measured absorption loading of CO2 in an aqueous amine solution showed a good linear relationship for the usual secondary and tertiary amines, indicating that the frontier orbital properties of these amines appear to be predominant for the amine-CO2 reaction.

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页码：189 / 190

页数：2

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