Homogeneous catalysis. Mechanisms of the catalysed Mukaiyama cross-aldol reaction

被引:12
作者
Ellis, WW [1 ]
Bosnich, B [1 ]
机构
[1] Univ Chicago, Dept Chem, Chicago, IL 60637 USA
关键词
D O I
10.1039/a705801b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
It is shown that [2 + 2] addition intermediates can form reversibly in the catalysed Mukaiyama reaction; these serve to prevent formation of the catalyst Me3Si+ and the reactivities of the [2 + 2] intermediates can affect the enantioselectivity of the reaction.
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页码:193 / 194
页数:2
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