Urease-catalyzed carbonate precipitation inside the restricted volume of polyelectrolyte capsules

被引：84

作者：

Antipov, A

Shchukin, D

Fedutik, Y

Zanaveskina, I

Klechkovskaya, V

Sukhorukov, G ^{[1
]}

Möhwald, H

机构：

[1] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany

[2] Phys Chem Res Inst, Minsk 220050, BELARUS

[3] Russian Acad Sci, Inst Crystallog, Moscow, Russia

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2003年 / 24卷 / 03期

关键词：

biomimetic synthesis; biomineralization; CaCO3; microencapsulation; polyelectrolyte capsule; urease;

D O I：

10.1002/marc.200390041

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new biomimetic approach for performing CaCO3 synthesis exclusively inside micron-sized polyelectrolyte capsules, based on the fermentative formation of a precipitative agent (CO32- anion) by urease-catalyzed urea hydrolysis, was developed. Precipitated CaCO3 completely fills the interior capsule volume and has a metastable waterite phase.

引用

页码：274 / 277

页数：4

共 23 条

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