Electrolytic partial fluorination of organic compounds - Part 26. Anodic monofluorination of ethyl isonicotinate

被引：13

作者：

Konno, A ^{[1
]}

Shimojo, M ^{[1
]}

Fuchigami, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Elect Chem, Yokohama, Kanagawa 226, Japan

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1998年 / 87卷 / 02期

关键词：

anodic monofluorination; ethyl isonicotinate; electrochemistry;

D O I：

10.1016/S0022-1139(97)00153-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Anodic fluorinations of ethyl isonicotinate (1) and related compounds have been attempted. Desired fluorinated product, 2-fluoroisonicotinate (2) was obtained in reasonable yield by direct anodic monofluorination of ethyl isonicotinate 1. The yield of 2 and the conversion of the electrochemical reaction could be improved by applying relatively lower anodic potential and by increasing the concentration of supporting electrolyte Et3N . 3HF. (C) 1998 Elsevier Science S.A.

引用

页码：137 / 140

页数：4

共 21 条

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