Triphenylbismuthine complexes of group 6 metal carbonyls:: X-ray crystal structures of [M(CO)5(BiPh3)] (M = Mo or W)

被引：37

作者：

Holmes, NJ ^{[1
]}

Levason, W ^{[1
]}

Webster, M ^{[1
]}

机构：

[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 545卷

关键词：

molybdenum; tungsten; chromium; bismuthine; X-ray structure;

D O I：

10.1016/S0022-328X(97)00236-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The [M(CO)(5)(BiPh3)] (M = Cr, Mo or W) complexes have been prepared from [M(CO)(5)(thf)] and BiPh3 in thf(thf = tetrahydrofuran), and characterised by analysis, FAB mass spectrometry, IR and C-13{H-1}-NMR spectroscopy, and the results compared with literature data on [M(CO)(5)(EPh3)] (E = P, As or Sb). The crystal structures of the Mo and W species have been determined (Mo-Bi 2.832(1), W-Bi 2.829(1) Angstrom). (C) 1997 Elsevier Science B.V.

引用

页码：111 / 115

页数：5

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