Electrochemical study of substituted triazoles adsorption on mild steel

被引:51
作者
Bentiss, F
Traisnel, M
Vezin, H
Lagrenée, M
机构
[1] ENSCL, CNRS UPRESA 8012, Lab Crystallochim & Physicochim Solide, F-59652 Villeneuve Dascq, France
[2] ENSCL, UPRES EA 2698, Lab Genie Proc Interact Fluides Reactifs Mat, F-59652 Villeneuve Dascq, France
[3] USTL, CNRS UPRESA 8009, Lab Chim Organ & Macromol, F-59655 Villeneuve Dascq, France
关键词
D O I
10.1021/ie000043o
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Two triazole derivatives were synthesized, and their inhibiting ability for scaling and corrosion process was checked using various electrochemical techniques. Potentiodynamic polarization studies clearly reveal the fact that triazole derivatives are good mixed-type inhibitors. Electrochemical impedance spectroscopy measurements confirm the corrosion inhibition ability of substituted triazolesin 1 M HCl. The inhibition efficiencies, calculated from these two techniques, are in reasonably good agreement and are very similar in the two cases, the more planar molecule being slightly better. The adsorption of these inhibitors is also found to obey the Langmuir adsorption isotherm.
引用
收藏
页码:3732 / 3736
页数:5
相关论文
共 32 条
[1]   The inhibition action of 1(benzyl)1-H-4,5-dibenzoyl-1,2,3-triazole on mild steel in hydrochloric acid media [J].
Abdennabi, AMS ;
Abdulhadi, AI ;
AbuOrabi, ST ;
Saricimen, H .
CORROSION SCIENCE, 1996, 38 (10) :1791-1800
[2]  
ALABDALLAH MM, 1991, KORROSION, V22, P150
[3]   3-PHENYL-1,2,4-TRIAZOL-5-ONE AS A CORROSION-INHIBITOR FOR COPPER [J].
ALKHARAFI, FM ;
ALHAJJAR, FH ;
KATRIB, A .
CORROSION SCIENCE, 1986, 26 (04) :257-264
[4]  
[Anonymous], 1993, CORROSION CHIMIE SUR
[5]   SURFACE ENHANCED RAMAN-SCATTERING AND IMPEDANCE STUDIES ON THE INHIBITION OF COPPER CORROSION IN SULFATE-SOLUTIONS BY 5-SUBSTITUTED BENZOTRIAZOLES [J].
ARAMAKI, K ;
KIUCHI, T ;
SUMIYOSHI, T ;
NISHIHARA, H .
CORROSION SCIENCE, 1991, 32 (5-6) :593-607
[6]   3,5-bis(n-hydroxyphenyl)-4-amino-1,2,4-triazoles and 3,5-bis(n-aminophenyl)-4-amino-1,2,4-triazoles:: a new class of corrosion inhibitors for mild steel in 1 M HCl medium [J].
Bentiss, F ;
Lagrenee, M ;
Traisnel, M ;
Mernari, B ;
Elattari, H .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1999, 29 (09) :1073-1078
[7]   Corrosion inhibition of mild steel in 1 M hydrochloric acid by 2,5-bis(2-aminophenyl)-1,3,4-oxadiazole [J].
Bentiss, F ;
Lagrenee, M ;
Traisnel, M ;
Hornez, JC .
CORROSION, 1999, 55 (10) :968-976
[8]   A simple one step synthesis of new 3,5-disubstituted-4-amino-1,2,4-triazoles [J].
Bentiss, F ;
Lagrenée, M ;
Traisnel, M ;
Mernari, B ;
Elattari, H .
JOURNAL OF HETEROCYCLIC CHEMISTRY, 1999, 36 (01) :149-152
[9]   The corrosion inhibition of mild steel in acidic media by a new triazole derivative [J].
Bentiss, F ;
Lagrenee, M ;
Traisnel, M ;
Hornez, JC .
CORROSION SCIENCE, 1999, 41 (04) :789-803
[10]  
CHADWICK D, 1980, CORROS SCI, V20, P887