A study on formation of regular honeycomb pattern in polysulfone film

被引:125
作者
Xu, Y [1 ]
Zhu, BK [1 ]
Xu, YY [1 ]
机构
[1] Zhejiang Univ, Inst Polymer Sci, Hangzhou 310027, Peoples R China
关键词
polysulfone; honeycomb films; water droplet;
D O I
10.1016/j.polymer.2004.12.001
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Regular polysulfone (PSF) honeycomb film with micron-sized cells was prepared by casting the solution in an atmosphere with high humidity. Water droplets acted as the template around which the PSF in the solution assemble. In this paper, the effects of atmosphere humidity, solution concentration, and the PSF molecular weight on pore size were discussed; the influence of storage time of casting solution on the pattern regularity was presented; the mechanism of pattern formation was proposed. (C) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:713 / 717
页数:5
相关论文
共 33 条
[1]   GROWTH OF BREATH FIGURES [J].
BEYSENS, D ;
KNOBLER, CM .
PHYSICAL REVIEW LETTERS, 1986, 57 (12) :1433-1436
[2]   HOW DOES DEW FORM [J].
BEYSENS, D ;
STEYER, A ;
GUENOUN, P ;
FRITTER, D ;
KNOBLER, CM .
PHASE TRANSITIONS, 1991, 31 (1-4) :219-246
[3]  
de Boer B, 2000, ADV MATER, V12, P1581, DOI 10.1002/1521-4095(200011)12:21<1581::AID-ADMA1581>3.0.CO
[4]  
2-R
[5]   Polymer films with a self-organized honeycomb morphology [J].
Francois, B ;
Pitois, O ;
Francois, J .
ADVANCED MATERIALS, 1995, 7 (12) :1041-&
[6]  
Govor LV, 2001, ADV MATER, V13, P588, DOI 10.1002/1521-4095(200104)13:8<588::AID-ADMA588>3.0.CO
[7]  
2-C
[8]   Coherent two-dimensional lasing action in surface-emitting laser with triangular-lattice photonic crystal structure [J].
Imada, M ;
Noda, S ;
Chutinan, A ;
Tokuda, T ;
Murata, M ;
Sasaki, G .
APPLIED PHYSICS LETTERS, 1999, 75 (03) :316-318
[9]   Ordered macroporous materials by emulsion templating [J].
Imhof, A ;
Pine, DJ .
NATURE, 1997, 389 (6654) :948-951
[10]   Template-directed preparation of macroporous polymers with oriented and crystalline arrays of voids [J].
Jiang, P ;
Hwang, KS ;
Mittleman, DM ;
Bertone, JF ;
Colvin, VL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (50) :11630-11637