Linking of metal centres through boryl ligands:: synthesis, spectroscopic and structural characterisation of a symmetrically bridged boryl complex CpFe(CO)2BO2C6H2O2BFe(CO)2Cp

被引:13
作者
Aldridge, S
Calder, RJ
Dickinson, AA
Willock, DJ
Steed, JW
机构
[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales
[2] Kings Coll London, Dept Chem, London WC2R 2LS, England
关键词
D O I
10.1039/b003901m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis, spectroscopic and structural characterisation of the symmetrically bridged boryl complex CpFe(CO)(2)- BO2C6H2O2BFe(CO)(2)Cp are reported, together with analysis of the bonding by structural and DFT methods.
引用
收藏
页码:1377 / 1378
页数:2
相关论文
共 21 条
  • [1] ALDRIDGE S, 2000, IN PRESS J ORGANOMET
  • [2] BAERENDS EJ, 1999, THEORETICAL CHEM
  • [3] DENSITY-FUNCTIONAL EXCHANGE-ENERGY APPROXIMATION WITH CORRECT ASYMPTOTIC-BEHAVIOR
    BECKE, AD
    [J]. PHYSICAL REVIEW A, 1988, 38 (06): : 3098 - 3100
  • [4] Braunschweig H, 1998, ANGEW CHEM INT EDIT, V37, P1786, DOI 10.1002/(SICI)1521-3773(19980803)37:13/14<1786::AID-ANIE1786>3.0.CO
  • [5] 2-C
  • [6] Braunschweig H, 1998, EUR J INORG CHEM, P291
  • [7] Diboran(4)yl groups as ligands to transition metals
    Braunschweig, H
    Ganter, B
    Koster, M
    Wagner, T
    [J]. CHEMISCHE BERICHTE, 1996, 129 (09) : 1099 - 1101
  • [8] Braunschweig H, 1998, EUR J INORG CHEM, P465
  • [9] TRANSITION-METAL-PROMOTED HYDROBORATIONS OF ALKENES, EMERGING METHODOLOGY FOR ORGANIC TRANSFORMATIONS
    BURGESS, K
    OHLMEYER, MJ
    [J]. CHEMICAL REVIEWS, 1991, 91 (06) : 1179 - 1191
  • [10] Phosphine exchange reactions involving cis-[Pt(PPh3)2(Bcat)2] (cat=1,2-O2C6H4) and the oxidative addition of 1,2-B2Cl2(NMe2)2 to Pt0
    Curtis, D
    Lesley, MJG
    Norman, NC
    Orpen, AG
    Starbuck, J
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (10): : 1687 - 1694