Spectroscopic properties of Gd3+-doped fluorozirconate glass

被引：72

作者：

Binnemans, K

Gorller-Walrand, C

Adam, JL

机构：

[1] Katholieke Univ Leuven, Dept Chem, Coordinat Chem Div, B-3001 Heverlee, Belgium

[2] Univ Rennes 1, Lab Verres & Ceram, UMR CNRS 6512, F-35042 Rennes, France

来源：

CHEMICAL PHYSICS LETTERS | 1997年 / 280卷 / 3-4期

关键词：

D O I：

10.1016/S0009-2614(97)01126-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The optical absorption and MCD spectrum of gadolinium-doped ZBLAN fluorozirconate glass were recorded at room temperature. The induced electric dipole contributions to the experimental dipole strengths were parametrized in terms of phenomenological Judd-Ofelt intensity parameters. The parameter set obtained by a standard least-squares fitting procedure is: Omega(2) = (3.35 +/- 0.62) X 10(-20) cm(2), Omega(6) = (2.81 +/- 0.08) X 10(-20) cm(2), and Omega(4), is indeterminate. Special attention is given to the characteristic spectroscopic properties of the Gd3+ ion. (C) 1997 Elsevier Science B.V.

引用

页码：333 / 338

页数：6

共 23 条

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[2] OPTICAL-PROPERTIES OF GD-3+ IN FLUOROZIRCONATE GLASSES [J].