Ionic radii for Group 1 halide crystals and ion-pairs

被引：13

作者：

Collin, RJ

Smith, BC

机构：

[1] Univ London Birkbeck Coll, Sch Biol & Chem Sci, London WC1E 7HX, England

[2] Cranleigh Sch, Cranleigh GU6 8QQ, Surrey, England

来源：

DALTON TRANSACTIONS | 2005年 / 04期

关键词：

D O I：

10.1039/b410521b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Internuclear separations calculated from empirical soft-sphere radii for seventeen crystalline Group 1 halides with rock-salt structures and from empirical hovering-sphere radii for fourteen gaseous Group 1 halide ion-pairs agree well with experimental measurements. Two lithium and four fluoride ion-pairs appear to be anomalous. Soft-sphere ionic radii are compared with atomic radii of noble gases.

引用

页码：702 / 705

页数：4

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