The reaction of cyclohexyl isocyanide and dimethyl acetylenedicarboxylate with o- and p-quinones:: a novel synthesis of iminolactones

被引：92

作者：

Nair, V ^{[1
]}

Vinod, AU

Nair, JS

Sreekanth, AR

Rath, NP

机构：

[1] CSIR, Div Organ Chem, Reg Res Lab, Trivandrum 695019, Kerala, India

[2] Univ Missouri, Dept Chem, St Louis, MO 63121 USA

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 34期

关键词：

isocyanides; acetylenedicarboxylate; quinones; iminolactones;

D O I：

10.1016/S0040-4039(00)01114-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 1:1 intermediate generated by the addition of cyclohexyl isocyanide to dimethyl acetylenedicarboxylate is trapped by quinones to yield iminolactones in good yields. (C) 2000 Published by Elsevier Science Ltd.

引用

页码：6675 / 6679

页数：5

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