Living cationic polymerizations utilizing an automated synthesizer: High-throughput synthesis of polyoxazolines

被引：68

作者：

Hoogenboom, R

Fijten, MWM

Meier, MAR

Schubert, US

机构：

[1] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands

[2] Dutch Polymer Inst, NL-5600 MB Eindhoven, Netherlands

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2003年 / 24卷 / 01期

关键词：

automated synthesis; combinatorial materials research; high-throughput experimentation; living cationic polymerization; parallel chemistry; poly(2-oxazoline)s;

D O I：

10.1002/marc.200390003

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Living cationic ring-opening polymerizations of 2-ethyl-2-oxazoline and purification of the resulting polymers were performed utilizing an automated synthetizer. Eight polymers (500 mg scale) as well as 40 polymers (150 mg scale) were synthesized in parallel to investigate the reproducibility and the living character of the polymerizations. The poly(2-ethyl-2-oxazoline)s obtained such were characterized by means of H-1 NMR spectroscopy, MALDI-TOF mass spectrometry and online gel permeation chromatography.

引用

页码：92 / 97

页数：6

共 30 条

[1]

[Anonymous], 2001, Angew. Chem

[2]

[Anonymous], ANGEW CHEM

[3] Polymerization of oxazolines [J].