Optical emission from confined poly(thiophene) chains

被引:31
作者
Inganas, O [1 ]
Granlund, T
Theander, M
Berggren, M
Andersson, MR
Ruseckas, A
Sundstrom, V
机构
[1] Linkoping Univ, IFM, Dept Phys, Appl Phys Lab, S-58183 Linkoping, Sweden
[2] Chalmers Univ Technol, S-41296 Gothenburg, Sweden
[3] Univ Lund, Dept Chem Phys, S-22100 Lund, Sweden
关键词
D O I
10.1016/S0925-3467(97)00062-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We discuss the stages of the luminescence processes in substituted and soluble poly(thiophenes), using results from determinations of absolute quantum yields of photoluminescence, fast pump-probe experiments and microcavity devices. Enhancement of the quantum yield of photoluminescence, with poly(thiophenes) in the solid state, call be obtained by dispersing the conjugated chain in a molecularly dispersed polymer blend, or by adding side chains designed for forcing the conjugated main chains apart. At the wavelength of stimulated emission, we observe a narrow bandwidth emission in the high-Q one-dimensional microcavity devices prepared by sandwiching two dielectric mirrors around a thin polymer film, A strong enhancement of the power efficiency is observed at a pump power of 1 mu W/cm(2), but does not conclusively show lasing characteristics. (C) 1998 Elsevier Science B.V.
引用
收藏
页码:104 / 108
页数:5
相关论文
共 24 条
[1]   Interaction of oxygen with conjugated polymers: Charge transfer complex formation with poly(3-alkylthiophenes) [J].
Abdou, MSA ;
Orfino, FP ;
Son, Y ;
Holdcroft, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (19) :4518-4524
[2]  
ANDERSSON M, 1991, POLYM COMMUN, V32, P546
[3]   ELECTROLUMINESCENCE FROM SUBSTITUTED POLY(THIOPHENES) - FROM BLUE TO NEAR-INFRARED [J].
ANDERSSON, MR ;
BERGGREN, M ;
INGANAS, O ;
GUSTAFSSON, G ;
GUSTAFSSONCARLBERG, JC ;
SELSE, D ;
HJERTBERG, T ;
WENNERSTROM, O .
MACROMOLECULES, 1995, 28 (22) :7525-7529
[4]   Influence of chain length and derivatization on the lowest singlet and triplet states and intersystem crossing in oligothiophenes [J].
Beljonne, D ;
Cornil, J ;
Friend, RH ;
Janssen, RAJ ;
Bredas, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (27) :6453-6461
[5]   LIGHT-EMITTING-DIODES WITH VARIABLE COLORS FROM POLYMER BLENDS [J].
BERGGREN, M ;
INGANAS, O ;
GUSTAFSSON, G ;
RASMUSSON, J ;
ANDERSSON, MR ;
HJERTBERG, T ;
WENNERSTROM, O .
NATURE, 1994, 372 (6505) :444-446
[6]   Polymer light-emitting diodes placed in microcavities [J].
Berggren, M ;
Inganas, O ;
Granlund, T ;
Guo, S ;
Gustafsson, G ;
Andersson, MR .
SYNTHETIC METALS, 1996, 76 (1-3) :121-123
[7]  
BERGGREN M, 1996, UNPUB DECOUPLING ELE
[8]  
BERGGREN M, UNPUB SOLID STATE DR
[9]  
BERGGREN M, 1996, CONTROLLING INTERCHA
[10]   Blue superradiance from neat semiconducting alternating copolymer films [J].
Brouwer, HJ ;
Krasnikov, VV ;
Hilberer, A ;
Hadziioannou, G .
ADVANCED MATERIALS, 1996, 8 (11) :935-&