Effect of Co substitution on the crystallization behavior and magnetic properties of melt-spun (Pr,Tb)2(Fe,Nb,Zr)14B/α-Fe nanocomposites

被引:7
作者
Wang, H [1 ]
Zhang, Y [1 ]
Jin, ZQ [1 ]
Hadjipanayis, GC [1 ]
机构
[1] Univ Delaware, Dept Phys & Astron, Newark, DE 19716 USA
关键词
D O I
10.1063/1.1558273
中图分类号
O59 [应用物理学];
学科分类号
摘要
The influence of Co substitution on the crystallization behavior and magnetic properties of (Pr,Tb)(2)(Fe,Nb,Zr)(14)B/alpha-Fe nanocomposites was investigated in melt-spun Pr7Tb1Fe87Nb0.5Zr0.5B4 and Pr7Tb1Fe57Co30Nb0.5Zr0.5B4 samples. Crystallographic textures were observed for all constituent phases in both sample S spun at wheel speeds less than 15 m/s. Both alloys show a fully amorphous structure when spun at a speed faster than 40 m/s which crystallizes into the TbCu7 structure before it finally transforms into the 2:14:1 phase. The Curie temperature of alpha-Fe and Pr2Fe14B phase increases greatly with the substitution of 30% Co for Fe. However, both the coercivity and energy product decrease. Optimum magnetic properties are found in the Pr7Tb1Fe87Nb0.5Zr0.5B4 sample with coercivity H-c=6.84 kOe and (BH)(max)=11.8 MG Oe. (C) 2003 American Institute of Physics.
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页码:7978 / 7980
页数:3
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