The chemical application of high-resolution electron tomography: Bright field or dark field?

被引:51
作者
Thomas, JM
Midgley, PA
Yates, TJV
Barnard, JS
Raja, R
Arslan, I
Weyland, M
机构
[1] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England
[2] UCL Royal Inst Great Britain, Davy Faraday Res Lab, London W1X 4BS, England
[3] Univ Cambridge, Chem Lab, Cambridge CB2 1EW, England
[4] Cornell Univ, Dept Appl & Engn Phys, Ithaca, NY 14853 USA
关键词
electron tomography; heterogeneous catalysis; nanoparticles; scanning probe microscopy;
D O I
10.1002/anie.200461453
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Visualizing 3D structures (especially of supported catalysts) by the nondestructive method of electron tomography is best accomplished by high-angle annular dark-field (HAADF) rather than by bright-field (BF) imaging; bimetallic clusters of [Ru10Pt2] (diameter ca. 0.4 nm), supported on nanoporous silica, are invisible in BF but readily visible in HAADF images (see pictures).
引用
收藏
页码:6745 / 6747
页数:3
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