Preparation and electrochemical properties of Ag-modified TiO2 nanotube anode material for lithium-ion battery

被引:321
作者
He, Ben-Lin [1 ]
Dong, Bin [1 ]
Li, Hu-Lin [1 ]
机构
[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China
基金
中国国家自然科学基金;
关键词
lithium-ion batteries; TiO2; nanotubes; Ag; cycling performance; high-rate discharge capacity;
D O I
10.1016/j.elecom.2006.10.008
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
TiO2 nanotubes prepared by using a hydrothermal process were firstly coated with silver nanoparticles as the anode materials for lithium-ion batteries by the traditional silver mirror reaction. The physical properties of the as-synthesized samples were investigated by X-ray diffraction and transmission electron microscopic. The as-prepared samples were used as negative materials for lithium-ion battery, whose charge-discharge properties, cyclic voltammetry, electrochemical impedance spectroscopy and cycle performance were examined in detail. The results showed that the Ag additive decreased the polarization of anode, and marvelously improved the high-rate discharge capacity and cycling stability of TiO2 nanotubes. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:425 / 430
页数:6
相关论文
共 27 条
  • [1] ABRHAM KM, 1993, ELECTROCHIM ACTA, V38, P1233
  • [2] AUBORN JJ, 1987, J ELECTROCHEM SOC, V134, P368
  • [3] BANFIELD JF, 1992, AM MINERAL, V77, P545
  • [4] BOMINO F, 1981, J POWER SOURCES, V6, P261
  • [5] LITHIUM INSERTION INTO LI2TI3O7
    CHEN, CJ
    GREENBLATT, M
    [J]. MATERIALS RESEARCH BULLETIN, 1985, 20 (11) : 1347 - 1352
  • [6] EHRLICH GM, 1997, JOINT INT M ABSTR, V97
  • [7] THIN-FILM CATHODES FOR SECONDARY LITHIUM BATTERIES
    FRAGNAUD, P
    NAGARAJAN, R
    SCHLEICH, DM
    VUJIC, D
    [J]. JOURNAL OF POWER SOURCES, 1995, 54 (02) : 362 - 366
  • [8] Synthesis and characterization of Li1+xMn2-xO4 for Li-ion battery applications
    Gao, Y
    Dahn, JR
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (01) : 100 - 114
  • [9] Electrochemical intercalation of lithium into the ramsdellite-type structure of Li2Ti3O7
    Garnier, S
    Bohnke, C
    Bohnke, O
    Fourquet, JL
    [J]. SOLID STATE IONICS, 1996, 83 (3-4) : 323 - 332
  • [10] Transport properties of LiMn2O4 electrode materials for lithium-ion batteries
    Guan, J
    Liu, ML
    [J]. SOLID STATE IONICS, 1998, 110 (1-2) : 21 - 28