Electron-transfer kinetics of nitroxide radicals as an electrode-active material

被引：156

作者：

Suga, T ^{[1
]}

Pu, YJ ^{[1
]}

Oyaizu, K ^{[1
]}

Nishide, H ^{[1
]}

机构：

[1] Waseda Univ, Dept Appl Chem, Tokyo 1698555, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2004年 / 77卷 / 12期

关键词：

D O I：

10.1246/bcsj.77.2203

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electron-transfer rate constants of nitroxide derivatives, 4-(N-t-butyl-N-oxylamino)-t-butylbenzene, 4-(N-t-butyl-N-oxylamino)methoxybenzene, and 2,2,6,6-tetramethylpiperidinyl-N-oxyl, were investigated by electrochemical methods, which demonstrated that these radicals can potentially be used as a high power-rate electrode-active material due to their fast electron-transfer process.

引用

页码：2203 / 2204

页数：2

共 8 条

[1]

Aurich H. G., 1989, Nitrones, Nitronates and Nitroxides, P313, DOI [10.1002/9780470772195, DOI 10.1002/9780470772195]

[2]

F Allen J Bard L.R., 2001, Electrochemical Methods: Fundamentals and Applications

[3] Antiferromagnetic exchange interaction among the three spins placed in an isosceles triangular configuration in 2,4-dimethoxy-1,3,5-benzenetriyltris(N-tert-butyl nitroxide) [J].