Canadian middle atmosphere model: Preliminary results from the chemical transport module

All important objective of middle atmosphere global climate modelling is the development of the capability of predicting the response of the middle atmosphere to natural or anthropogenic perturbations. To achieve this, a comprehensive chemistry package interactively coupled with radiative and dynamical modules is required This paper presents preliminary results obtained with a photochemistry module which has been incorporated in the Canadian Middle Atmosphere Model (CMAM). The module contains 42 species including necessary oxygen, hydrogen, nitrogen, chlorine, bromine and methane oxidation cycle species. Photochemical balance equations are solved on-line throughout the middle atmosphere at every dynamical time step. A full diurnal cycle is simulated with photolysis rates provided by a look-up table. The chemistry solver is a mass conserving, fully implicit, backward difference scheme which currently uses less than 10% of the CCM run time. We present the results obtained from short integrations and compare them with UARS measurements. The model ozone distribution appears in quantitative agreement with observations showing peak values near 10 ppmv and confined to the 35-km region. The abundance of nitrogen, chlorine, bromine oxides and their respective contributions to the overall ozone budget is realistic. The study illustrates the capability of the model to simulate middle atmosphere photochemistry for the disparate conditions occurring throughout the region.